Hui Chi-kin was born in Hong Kong and started learning violin at the age of five. He studied with Ng Ka-ming at the Music Office in Hong Kong. After graduating from the Hong Kong Polytechnic University he studied at The Hong Kong Academy for Performing Arts under Leung Kin-fung and graduated with a Bachelor of Music degree. In 2004 he was awarded a full scholarship to participate in the Kirishima International Music Festival in Japan. Hui Chi-kin has performed with the Macao Orchestra, the Hong Kong Virtuosi and the Macao Virtuosi. He has also performed on tour in mainland China many times with these orchestras. He became a member of City Chamber Orchestra of Hong Kong in 2015.